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Isolation and characterization of a novel polysaccharide from seeds of Peltophorum pterocarpum

机译:翼龙果种子中一种新型多糖的分离与鉴定

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摘要

Peltophorum pterocarpum seeds yielded ~20% water soluble polysaccharide. The polysaccharide is a galactomannan with mannose:galactose ratio of 4.4:1. The polysaccharide had an intrinsic viscosity of 3.14 dl/g and weight average molecular weight of 2.49 x 105 g/mol. The polysaccharide solutions were non-Newtonian at concentrations above 1%. A double logarithmic plot of the zero shear specific viscosity versus volume concentration gave a coil overlap concentration, c* of 2.6/[η], with slope c1.4 in the dilute regime and c4.3 in the concentrated regime. The experimental data were fitted to different viscosity models with the Martin model giving the best fit. The Cox-Merz empirical rule gave close superimposition of the data from steady shear viscosity η( ) and complex viscosity η*(ω).
机译:翼果蕨种子产生约20%的水溶性多糖。多糖是半乳甘露聚糖,其甘露糖:半乳糖比率为4.4∶1。该多糖的特性粘度为3.14dl / g,重均分子量为2.49×105g / mol。多糖溶液是浓度高于1%的非牛顿溶液。零剪切比粘度对体积浓度的双对数图给出了线圈重叠浓度,c *为2.6 / [η],在稀薄状态下为c1.4,在浓缩状态下为c4.3。将实验数据拟合到不同的粘度模型,其中马丁模型给出了最佳拟合。 Cox-Merz经验法则给出了稳态剪切粘度η()和复数粘度η*(ω)的数据的紧密叠加。

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